B.A. MEng, Chemical Engineering, University of Cambridge, 1995
PhD, Chemical Engineering, Princeton University (USA) 2000
Film Formation and dispersion drying
When a dispersion of stable colloidal particles is dried the particles pack and form a solid network. If the particles are weak enough they deform and a continuous film, with a particle volume fraction of unity is formed. For polymeric particles, interdiffusion of polymer chains blurs out the existence of the original particles and a continuous polymer film is created. This process is called film formation.
An EU project is examining film formation using composite particles, where a hard component such as clay or silica is embedded within the polymer particles. We have modelled the deformation of such particles and followed the stress development in a film using a beam bending technique.
For harder particles the film is weak and displays cracks. The crack pattern and spacing has been the subject of much work and we have shown how flow of solvent away from defects in the film set the spacing and lead to a stick-slip motion of the crack through the drying film. A current project in collaboration with Dr Bill Clegg in Materials Science is examining the forces at play as the cracks develop.
As a film dries the particles will distribute themselves. Using a distribution in particle sizes it is possible to create gradients in particle concentraions and hence film properties. This is a self assembly type mechanism for stratification.
When colloidal particles attract each other they will form macroscopic clumps, called flocs and the process by which this happens is called aggregation. We are studying this in two separate systems
Engine oil additives
Engine oil contains 5 nm calcium carbonate particles and these are stabilised by the use of surfactants. Under certain circumstances the particles become unstable and we are elucidating the mechanism using light scattering, rheology and small angle neutron scattering. We are also using thermodynamics to predict the phase diagram in systems containing free polymer and comparing our theoretical results with experiment.
We make a number of encapsulated systems: In one project we are seeking to encapsulate enzymes in an aqueous core surrounded by a polymeric shell. The shell is responsive, allowing the biological reaction to be externally controlled. Encapsulation is carried out in colloidosomes with a self - assembly approach used.
In a different project we are seeking to make organic core capsules with a shell that slowly dissolves. This enables controlled release of active for a number of application.
Microgels are latex particles that respond to their external environment by sewlling. An example is particles based on poly(N-isopropylacrylamide) which are swollen at temperatures below 32oC and collapsed at higher temperatures. We have examined the thermodynamics of the collapse as well as the fluid mechanics of solvent flow around and through such particles.
Collaborators outside this directory
- Dr Bill Clegg
Wai Peng Lee and Alexander F. Routh, Temperature dependence of crack spacing in drying latex films, Industrial & Engineering Chemistry Research, 45 6996-7001 2006.
Wai Peng Lee, Venkata R. Gundabala, Belinda Akpa, Michael L. Johns, Chris Jeynes and Alexander F. Routh, Distribution of surfactant in latex films: a Rutherford Back Scattering study, Langmuir 22 (12): 5314-5320 2006.
Alexander F. Routh, Alberto Fernando Nieves, Melanie Bradley and Brian Vincent, Effect of free polymer on the swelling of neutral microgels: A thermodynamic approach, Journal of Physical Chemistry 110(25): 12721-12727 2006
Huai Nyin Yow and Alexander F. Routh, Formation of Liquid core polymer shell microcapsules, Soft Matter 2 940-949 2006.
J. W. Tavacoli, P. J. Dowding, D. C. Steytler, D. J. Barnes and A. F. Routh, Where does water go in overbased sulphonate engine oil additives?, Langmuir 24(8): 3807-3813 2008
Huai Nyin Yow and Alexander F. Routh, Colloidal buckets formed by internal phase separation, Soft Matter 4(11): 2080-2085 2008.
Andrew Howe, Stéphanie Desrousseaux, Laure Lunel, Joseph Tavacoli, Huai Nyin Yow and Alexander F. Routh , Anomalous viscosity jump during the volume phase transition of poly(N-isopropylacrylamide) particles, Advances in Colloid and Interface Science 147-148: 124-131 2009.
Venkata R. Gundabala, Chun-Hong Lei, Keltoum Ouzineb, Olivier Dupont, Joseph L. Keddie, and Alexander F. Routh, Lateral surface non-uniformities in drying latex films, AIChE J 54(12): 3092-3105 2008.